MOFCOF composites a review of synthesis methods and applications
Subject Areas :Milad Ghani 1 , Marziyeh Kavian 2
1 -
2 -
Keywords: MOF, COF, MOF@COF composites, Applications,
Abstract :
In the past decades, porous materials have attracted a lot of attention in physics, chemistry and materials science. Among various compounds, metal-organic frameworks (Metal organic frameworks, MOFs) and covalent organic frameworks (COFs), as crystalline porous materials, were developed at a very high speed. MOFs are a subgroup of porous compounds in which organic ligands are connected together with metal cations. COFs are two- or three-dimensional organic solids with extended structures in which the building blocks are connected by strong covalent bonds. These compounds have unique advantages including well-defined and tunable structures, large surface area, high porosity, and ease of framework modification, which make them ideal host substrates for various guests including polymers, metal oxide nanoparticles, and semiconductors to create Converts MOF or COF-based multistructures. Compared to single-component compounds, polycomposites always show new properties due to their synergistic effects. Therefore, to further improve their performance and expand their applications, many efforts have been made to design and fabricate various MOF or COF-based multi-structures. Therefore, in this study, the integration of MOFs and COFs, their manufacturing methods, and the applications of these multiple structures will be investigated. Moreover, the capability of the prepared sorbents in various fields such as sorbent, catalysis and other format will be discussed. Metal–organic frameworks (MOFs) are a class of compounds consisting of metal clusters (also known as SBUs) coordinated to organic ligands to form one-, two-, or three-dimensional structures.
[1] Cote A. P., Benin A. I., Ockwig N. W., O'Keeffe M., Matzger A. J., & Yaghi O. M., Porous, crystalline, covalent organic frameworks, science, 310, 1166-1170, 2005.
[2] Lyu H., Ji, Z., Wuttke S., & Yaghi O. M., Digital reticular chemistry, Chem, 6, 2219-2241, 2020.
[3] Ding M., Flaig R. W., Jiang H. L., & Yaghi O. M., Carbon capture and conversion using metal–organic frameworks and MOF-based materials, Chemical Society Reviews, 48, 2783-2828, 2019.
[4] Cai G., Yan P., Zhang L., Zhou H. C., & Jiang H. L., Metal–organic framework-based hierarchically porous materials: synthesis and applications, Chemical Reviews, 121, 12278-12326, 2021.
[4] Tian Y., & Zhu G., Porous aromatic frameworks (PAFs), Chemical reviews, 120, 8934-8986, 2020.
[6] Furukawa H., Cordova K. E., O’Keeffe M., & Yaghi O. M., The chemistry and applications of metal-organic frameworks, Science, 341, 1230444, 2013.
[7] Geng K., He T., Liu R., Dalapati S., Tan K. T., Li Z., & Jiang D., Covalent organic frameworks: design, synthesis, and functions, Chemical Reviews, 120, 8814-8933, 2020.
[8] Dong J., Tan C., Zhang K., Liu Y., Low P. J., Jiang J., & Cui Y., Chiral NH-controlled supramolecular metallacycles, Journal of the American Chemical Society, 139, 1554-1564, 2017.
[9] Yaghi O. M., & Li, H., Hydrothermal synthesis of a metal-organic framework containing large rectangular channels, Journal of the American Chemical Society, 117, 10401-10402, 1995.
[10] Chowdhury P., Bikkina C., & Gumma S., Gas adsorption properties of the chromium-based metal organic framework MIL-101, The Journal of Physical Chemistry C, 113, 6616-6621, 2009.
[11] Ding S. Y., & Wang W., Covalent organic frameworks (COFs): from design to applications, Chemical Society Reviews, 42, 548-568, 2013.
[12] Kang I. J., Khan N. A., HaqueE., & Jhung S. H., Chemical and thermal stability of isotypic metal–organic frameworks: effect of metal ions, Chemistry–A European Journal, 17, 6437-6442, 2011.
[13] Cui J., Feng Y., & Jia S., Silica encapsulated catalase@ metal-organic framework composite: A highly stable and recyclable biocatalyst, Chemical Engineering Journal, 351, 506-514, 2018.
[14] Ding M., & Jiang H. L., Improving water stability of metal–organic frameworks by a general surface hydrophobic polymerization, CCS Chemistry, 3, 2740-2748, 2021.
[15] Li Y. M., Yuan J., Ren H., Ji C. Y., Tao Y., Wu Y., & Cheng L., Fine-tuning the micro-environment to optimize the catalytic activity of enzymes immobilized in multivariate metal–organic frameworks, Journal of the American Chemical Society, 143, 15378-15390, 2021.
[16] Ma M., Lu X., Guo Y., Wang L., & Liang X., Combination of metal-organic frameworks (MOFs) and covalent organic frameworks (COFs): Recent advances in synthesis and analytical applications of MOF/COF composites, TrAC Trends in Analytical Chemistry, 116741, 2022.
[17] Peng Y., Zhao M., Chen B., Zhang Z., Huang Y., Dai F., & Zhang H., Hybridization of MOFs and COFs: a new strategy for construction of MOF@ COF core–shell hybrid materials, Advanced materials, 30, 1705454, 2018.
[18] Feng L., Wang K. Y., Lv X. L., Yan T. H., Li J. R., & Zhou H. C., Modular total synthesis in reticular chemistry, Journal of the American Chemical Society, 142, 3069-3076, 2020.
[19] Li F., Wang D., Xing Q. J., Zhou G., Liu S. S., Li Y., & Zou J. P., Design and syntheses of MOF/COF hybrid materials via postsynthetic covalent modification: An efficient strategy to boost the visible-light-driven photocatalytic performance, Applied Catalysis B: Environmental, 243, 621-628, 2019.
[20] He S., Rong Q., Niu H., & Cai Y. Platform for molecular-material dual regulation: A direct Z-scheme MOF/COF heterojunction with enhanced visible-light photocatalytic activity, Applied Catalysis B: Environmental, 247, 49-56, 2019.
[21] Zhang F. M., Sheng J. L., Yang Z. D., Sun X. J., Tang H. L., Lu M., & Lan Y. Q., Rational design of MOF/COF hybrid materials for photocatalytic H2 evolution in the presence of sacrificial electron donors, Angewandte Chemie International Edition, 57, 12106-12110, 2018.
[22] Sun D., & Kim D. P., Hydrophobic MOFs@ metal nanoparticles@ COFs for interfacially confined photocatalysis with high efficiency, ACS applied materials & interfaces, 12, 20589-20595, 2020.
[23] Sun W., Tang X., Yang Q., Xu Y., Wu F., Guo S., & Wang Y. Coordination‐induced interlinked covalent‐and metal–organic‐framework hybrids for enhanced lithium storage, Advanced Materials, 31, 1903176, 2019.
[24] Firoozi M., Rafiee Z., & Dashtian, K. New MOF/COF hybrid as a robust adsorbent for simultaneous removal of auramine O and rhodamine B dyes, ACS omega, 5, 9420-9428, 2020.
[25] Das S., Ben T., Qiu S., & Valtchev V., Two-dimensional COF–three-dimensional MOF dual-layer membranes with unprecedentedly high H2/CO2 selectivity and ultrahigh gas permeabilities, ACS Applied Materials & Interfaces, 12, 52899-52907, 2020.
[26] Liu X., Hu M., Wang M., Song Y., Zhou N., He L., & Zhang Z., Novel nanoarchitecture of Co-MOF-on-TPN-COF hybrid: Ultralowly sensitive bioplatform of electrochemical aptasensor toward ampicillin, Biosensors and Bioelectronics, 123, 59-68, 2019.
[27] Li M., Qiao S., Zheng Y., Andaloussi Y. H., Li, X., Zhang Z., & Chen Y., Fabricating covalent organic framework capsules with commodious microenvironment for enzymes, Journal of the American Chemical Society, 142, 6675-6681, 2020.
