Geochemical Study and Genetic Classification of Fahlian Reservoir Oil Using Infrared Spectroscopy in the Fields of Southwestern Iran
Subject Areas : GeochemistryMohammad Ali Sahmoradi 1 , Mohammad Hossein Saberi 2 , Bahman Zare nejad 3 , Ali Chehrazi 4
1 - دانشگاه سمنان
2 - دانشگاه سمنان
3 - دانشگاه سمنان
4 - شرکت ملی نفت ایران
Keywords: crude oil Fourier transform infrared (FTIR) spectroscopy Oil-oil correlation Fahlian reservoir,
Abstract :
The first step in performing geochemical adaptations is to identify the molecular and hybrid structure of the oil. One way to match the use of infrared spectroscopy is to identify and compare the structure of oil samples. Infrared spectroscopy is a practical method with easy, low-cost interpretation and reliable results for determining the structure of organic compounds. Also, considering the significant growth of the tendency to develop fast, accurate and reliable analytical methods for industrial applications and also the discovery of new hydrocarbon resources in the sedimentary basin of Abadan plain such as Darkhoein and Yadavaran oil fields in recent years, indicates the need for more comprehensive studies. There is a sedimentary basin in this basin. Based on this, 15 samples of crude oil from Fahlian reservoir were selected and examined in the most important oil fields of this basin, namely Darkhoein (9 samples) and Yadavaran (6 samples) located in southwestern Iran. By dividing the samples by evaluating the crude oil, different analytical goals were achieved. Using infrared spectroscopy, the functional groups in the samples were determined and then the amount of these compounds in different samples was compared with each other. Based on the results of the mass spectrometer, the oils studied in this basin are divided into three families with different genetic characteristics. In this study, it was shown that infrared spectrometer is a fast, reliable and non-destructive analytical option and a complementary or even alternative method of chromatography and biomarkers analysis to perform various scientific and industrial purposes in the oil industry, including quality measurement, Quantity and geochemical evaluation of oil.
[1] افتخارنژاد، ج. تفکیك بخشهای مختلف ايران ازنظر وضع ساختمانی در ارتباط با حوضه- های رسوبی، نشريه انجمن نفت شماره 82 ،صفحه 19-28 ،1358.
[2] الهام اسدی مهماندوستی و همکاران،1395،ارزیابی ژئوشیمیایی نفت های خام مخازن سروک و فهلیان با استفاده از داده های بیومارکری در یکی از میادین نفتی در دشت آبادان،نشریه علمی-پژوهشی زمین شناسی نفت ایران،سال پنجم،شماره10،زمستان1394،صفحه66-46.
[3] بهرام علیزاده1391، مطالعه ژئوشيميايي و تأثير كاني ماتريكس بر پتانسيل سنگهاي منشأ احتمالي ميدان نفتي دارخوين واقع در دشت آبادان،Archiv of SID،www.SID.ir.
[4] بهرام علیزاده و همکاران1395،مطالعه ایزوتوپی نفت مخازن گروه بنگستان در برخی از میادین دشت آبادان، جنوب غرب ایران. مجله زمین شناسی کاربردی پیشرفته،تابستان 95 ، شماره 2
[5] حسن محسنی،موسی اسفندیاری،محمد علی کاووسی،1394، فرآيندهای دياژنزی و چینهنگاری سکانسی سازند فهلیان در میدان نفتی يادآوران (کوشک و حسینیه) در فروافتادگی دزفول شمالی، نشریه علمی-پژوهشی رخساره های رسوبی،پاییز و زمستان1394،شماره8،صفحه236-255
[6] حقی پور و همکاران 1358 ،شرح نقشه زمین شناسی زاگرس، مقیاس 111111/1 گزارش شماره A3 ،صفحه58.
[7] مرتضی طاهری نژاد، مرتضی آسمانی، احمدرضا ربانی.1395.طبقه بندی ژنتیکی نفت های میادین شرق خلیج فارس با استفاده از طیف سنجی مادون قرمز نمونه های آسفالتین. نشریه علمی-پژوهشی زمین شناسی نفت ایران. سال ششم،شماره12، پاییز و زمستان 1395.صفحه 79-60.
[8] فاطمه باسره، مرتضی طاهری نژاد، احمدرضا ربانی، مرتضی آسمانی.1395.مطالعه طیف سنجی مادون قرمز نمونه های آسفالتین استخراج شده از نفت خام میادین خلیج فارس.سومین کنفرانس بین المللی نوآوری های اخیر در شیمی و مهندسی شیمی.18 شهریورماه 95 تهران.
[9] مطیعی،ه،1372.زمین شناسی ایران-زمین شناسی نفت زاگرس:سازمان زمین شناسی و اکتشاف معدنی کشور، صفحه572.
[10] مطیعی،ه، 1374 .زمینشناسی نفت زاگرس، سازمان زمینشناسی کشور، چاپ نخست،صفحه589.
[11] A.Permanyer, C. Rebufa , J. Kister.(2007). Reservoir compartmentalization assessment by using FTIR spectroscopy. Journal of Petroleum Science and Engineering 58. 464–471.
12] Belliny, M., Catacchini, E., Natale, D.P., Di Lonardo G., Fusina L. and Inguscio M. (1995) ‘Coherent FTIR spectroscopy of molecules of atmospheric interest’, Infrared Physics & Technology 36, 37-44.
[13] Christy, A.A., Hopland, A.L., Barth, T., Kvalheim, O.M., 1989. Quantitative determination of thermal maturity in sedimentary organic matter by diffuse reflectance infrared spectroscopy of asphaltenes. Organic Geochemistry 14, 77– 81.
[14] Davis J C(1986) Statistics and data analysis in geology. John wiley & sons Inc New York,646p
[15] Doumenq, P., Guiliano, M., Mille, G., Kister, J., 1991. Approche méthodologique directe et continue du processus
d'oxydation des bitumes par spectroscopie infrarouge à Transformée de Fourier. Analytica Chimica Acta 242, 137–141. [16] Guiliano, M., Mille, G., Kister, J., Muller, J.F., 1988. Etude des spectres IRTF de charbon français déminéralisés et de leurs macéraux. Journal de Chimie Physique 85, 963–970.
[17] Hwang RJ, Ahmed AS, Moldowan JM. Org Geochem 1994;21: 171–88.
[18] Hwang RJ, Baskin DK. Middle East Pet Geosci Geo 1994;94(2): 529–41.
[19] Mayo,D.W.,F.A.Miller,and R.W.Hannah,(2004), Course notes on the interpretation of infrared and Raman spectra, Wily Online Library.
[20 Mohammadreza Khanmohammadi,Amir Bagheri Garmarudi, Miguel de la Guardia.2012. Characterization of petroleumbased products by infrared spectroscopy and chemometrics. Trends in Analytical Chemistry, Vol. 35.
[21] Moschopedis, S.E., Parkash, S. and Speight, J., 1979, Themal decomposition of asphaltens . Fuel,57,431-434.
[22] Nosrati K, Derfishi Kh, Gharehchahi S, Rahimi Kh.(2011) Surface water quality assessment of the Haraz-Gharesh souz basin using multivariate statical techniques. Knowledge of Earth science 2(5):41-55.
[23] Pavia,D.L.,Lampaman, G. M.,Kriz, G. S., and Vyvyan,j. A.(2008),Introduction to spectroscopy. Cengage Learning.
[24] Pelet, R., Behar, F. and Monin, J. C., 1986, Resins and asphaltenes in the generation and migration of petroleum. Organic geochemistry,10(1-3),481-498.
[25] Pieri, N., Planche, J.P., Kister, J., 1996. Caractérisation structurale des bitumes routiers par IRTF et Fluorescence UV en mode excitation émission synchrones. Analysis 24, 113–122.
[26] Permanyer, A., Douifi, Dupuy, N., Lahcini, A., Kister, J., 2005. FTIR and SUVF spectroscopy as an alternative method in reservoir studies. Application to Western Mediterranean oils. Fuel 84, 159–168.
[27] Permanyer , D.A. Azevedo , C. Rébufa , J. Kister y F.T.T. Gonçalves.2005. Characterization of Brazilian oils by FTIR and
SUVF spectroscopy. A comparison with GC/MS results. Geogaceta, 38 (2005), 139-141 ISSN: 0213683X. [28] Permanyer, A., Douifi, L., Lahcini, A., Lamontagne, J., Kister, K., 2002a. FTIR and SUVF spectroscopy applied to reservoir compartmentalization: a comparative study with gas chromatography fingerprints results. Fuel 81 (7), 861–866.
[29] Permanyer, A., Douifi, L., Alberdi, M., Rebuffa, C., Kister, J., 2002b. Reservoir compartmentalization and oil maturity determined by FTIR. Proceedings of 8th Latin-American Congress on Organic Geochemistry, pp. 111–114.
[30] Peters, K. E. and M. G. Fowler (2002). "Applications of petroleum geochemistry to exploration and reservoir management." Organic Geochemistry 33(1): 5-36.
[31] Rouessac, F. and A. Rouessac, Chemical analysis: modern instrumentation methods and techniques. 2013: John Wiley & Sons.
[32] Saadatinejad, M. R. and K. Sarkarinejad (2011). "Application of the spectral decomposition technique for characterizing reservoir extensional system in the Abadan Plain, southwestern Iran." Marine and Petroleum Geology 28(6): 1205-1217.
[33] Shrestha S, Kazama F.(2007) Assessment of surface water quality using multivariate statical techniques: A case study of the Fuji river basin,Japan. Jurnal of Environmental Modeling & Software 22(4):464-475.
[34] Stat Soft Inc (2004) STATISTICA (Data Analysis Software System),Version 6.
[35] Usunoff E J, Guzma n-ghuzma n A(1989) Multivariate analysis in hydrochemistry: an example of the use of factor and
correspondence analyses. Ground Water27(1):27-34.
