بررسی رفتار زمین‌شیمیایی عناصر اصلی و کمیاب خاکی در گارنت‌های پگماتیت‌های دره ولی (شمال شرق بروجرد، پهنه سنندج- سیرجان)
الموضوعات :
سمیه رحمانی جوانمرد
1
( دانشگاه لرستان، خرم¬آباد)
زهرا طهماسبی
2
(دانشگاه لرستان)
زینک دینک
3
( اکادمی علوم چین، گوانجو)
احمد احمدی خلجی
4
( دانشگاه لرستان، خرم¬آباد)
الکلمات المفتاحية: بروجرد پگماتيت دره ولی زمین‌شیمی عناصر کمیاب خاکی گارنت ماگمایی,
ملخص المقالة :
پگماتیت‌های منطقه دره ولی در شمال شرق بروجرد و در پهنه ساختاری سنندج- سیرجان واقع شده‌اند. این پگماتیت‌ها به‌صورت دایک‌هایی با روند شمال‌غرب- جنوب‌شرق، واحدهای گرانودیوریتی منطقه مورد مطالعه را قطع کرده‌اند. این سنگ‌ها از نظر کانی‌شناسی شامل کانی‌های کوارتز، فلدسپار‌های آلکالن (ارتوکلاز و میکروکلین)، پلاژیوکلاز، مسکوویت، گارنت (آلماندین- اسپسارتین)، آندالوزیت، تورمالین و آپاتیت هستند. الگو‌های REE بهنجار‌شده نسبت به كندريت در پگماتیت‌های دره ولی، بیانگر غنی‌شدگی اندک LREE نسبت به HREE )04/4-76/1(LaN/YbN=، الگوی نسبتاً مسطح HREE و بی‌هنجاری منفی شدید Eu (54/0-20/0 (Eu/Eu*= است. بررسی شيمي عناصر اصلي گارنت‌هاي درون اين پگماتيت‌ها بيانگر منطقه‌بندی ترکیبی با افزایش FeO و کاهش MnO از مرکز به حاشیه است. مقادیر بسيار بالاي منگنزwt.%) 18/13-27/10 (MnO= و مقدار کم کلسيمwt.%) 29/0-15/0(CaO= گارنت‌هاي موجود در پگماتيت دره ولی، مشابه گارنت‌هاي ماگمايي درون مذاب‌هاي پگماتيتي است. ترکیب بلور‌های گارنت بر روی نمودار MnO+CaO در مقابل FeO+MgO (برحسب درصد وزنی)، بیانگر تبلور آنها در بخش حاشیه‌ای رگه پگماتیتی و از مذاب‌های کم‌تر تفریق‌یافته است. نتایج LA-ICP-MS حاکی از غنی‌شدگی گارنت‌های مورد مطالعه از عناصر کمیاب خاکی سنگین (HREE)، تهی‌شدگی از عناصر کمیاب خاکی سبک (LREE) و بی‌هنجاری منفی شدید Euدر مرکز )41/0-0(Eu/Eu*= و مثبتEu )22/3-0(Eu/Eu*= در حاشیه‌ها است. عناصر Y، HREE، Ti، Zr، Nb، Ta، Hf، U و Mn از مرکز به سمت حاشیه کاهش نشان می‌دهند. این تغییرات از مرکز به حاشیه، به افزایش فاز سیال و اکتیویته H2O در ماگما و افزایش تفریق ماگمایی نسبت داده شده است. الگوی REE و بی‌هنجاری‌های Eu در گارنت‌های دارای منطقه‌بندی، بیانگر تبلور آنها در شرایط احیایی تا اکسیدان است.
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