کاربرد نقاط کوانتومی کربن (CQDs) در فناوری های غشایی: مروری
محورهای موضوعی : پليمرها و نانوفناوری
فرزاد مهرجو
1
(دانشگاه بیرجند)
کلید واژه: نقاط کوانتومی کربن, نقاط کوانتومی گرافن اکسید, جداسازی غشایی, ضدرسوب,
چکیده مقاله :
نقاط کوانتومی کربن (Carbon Quantum Dots)، که یک کلاس جذاب از کربن‌های نانوساختار هستند، اخیراً توجه گسترده‌ای را در زمینه فناوری‌های غشایی برای کاربردهایشان در فرآیندهای جداسازی به خود جلب کرده‌اند. این به این دلیل است که آن ها دو مزیت منحصر به فرد دارند. تولید آن ها آسان و ارزان است، در حالی که خواص فیزیکوشیمیایی آن ها مانند اندازه های بسیار کوچک، زیست سازگاری خوب، بی اثری شیمیایی بالا، آب دوستی قابل تنظیم، غنی از گروه های عملکردی سطحی و ویژگی های ضدرسوب بسیار مطلوب هستند. محققان با استفاده از این موارد، کاربرد آن ها را در طرح‌های مختلف غشاء برای اسمز معکوس (Reverse Osmosis)، اولترافیلتراسیون (Ultrafiltration)، نانوفیلتراسیون (Nonofiltration)، اسمز مستقیم (Forward Osmosis)، اسمز عقب مانده فشاری (Pressure Retarded Osmosis)، تقطیر غشایی (Membrane Distillation) و فرآیندهای نانوفیلتراسیون حلال آلی (Organic Solvent Nanofiltration) مورد بررسی قرار دادند. به طور خاص، CQDs به ویژه اکتشاف در زمینه تصفیه آب توسط فناوری های غشایی را تحریک کرده اند، زیرا زیست سازگاری مواد غشایی برای اطمینان از ایمنی آب آشامیدنی از اهمیت بالایی برخوردار است. علاوه بر این، CQDs در موقعیت مطلوبی برای دستیابی به عملکرد بی سابقه فرآیندهای جداسازی غشایی در تصفیه آب، با توجه به افزایش کارایی قابل توجه و تمایل ضدرسوب، همان طور که در تحقیق های اخیر کشف شده است، قرار دارند. در این مقاله، پیشرفت در توسعه غشاهای CQDs گنجانده شده را با بحث در مورد چالش ها و دیدگاه های آن ها بررسی شده است.
Applications of Carbon Quantum Dots (CQDs) in Membrane Technologies: A Review Carbon quantum dots (CQDs), which are a fascinating class of nanostructured carbons, have recently attracted extensive attention in the field of membrane technologies for their applications in separation processes. This is because they possess two unique advantages. Their productions are facile and inexpensive, while their physicochemical properties such as ultra-small sizes, good biocompatibility, high chemical inertness, tunable hydrophilicity, rich surface functional groups and antifouling characteristics are highly desirable. Leveraging on these, researchers have explored their utilizations in various membrane designs for reverse osmosis (RO), ultrafiltration (UF), nanofiltration (NF), forward osmosis (FO), pressure retarded osmosis (PRO), membrane distillation (MD), and organic solvent nanofiltration (OSN) processes. In particular, CQDs have especially stimulated exploration in the field of water treatment by membrane technologies since biocompatibility of membrane materials is of utmost importance to ensure safety of drinking water. In addition, CQDs are in a favorable position for achieving unprecedented performance of membrane separation processes in water treatment, in the light of substantial efficiency enhancement and antifouling propensity as discovered in recent studies. In this article, we will review the progress in the development of CQD incorporated membranes with discussions on their challenges and perspectives.
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