غشاهای دریچه هوشمند
محورهای موضوعی :
1 - تهران
کلید واژه: غشا هوشمند دریچه محرک,
چکیده مقاله :
غشا و فرایندهای غشایی نقش مهمی در توسعه پایدار زمینه های بی شماری مانند انرژی، مدیریت زیست محیطی و سلامت انسان ایفا می کنند. با این حال، غیر قابل تغییر بودن اندازه منافذ و خواص سطح غشاهای تجاری، کاربرد موثرآن ها را محدود کرده است. به منظور ارتقای کارایی غشاهای تجاری، غشاهای جدیدی با الهام از غشای سلولی و با استفاده از ترکیب غشاهای معمول و مواد پاسخگو به عوامل تحریک خارجی به عنوان غشاهای هوشمند ساخته شد هاست. غشاهای با دریچه هوشمند، مزیت های بسیاری نسبت به غشاهای معمولی دارند. از جمله تنظیم نفوذپذیری و انتخاب پذیری بر اساس تغییر حالت '' باز / بسته '' دریچه ها در پاسخ به تحری کهای محیطی. در این مقاله مروری به صورت خلاصه تحولات اخیر در زمینه غشاهای پاسخگو به تحری کهای محیطی، از جمله رهیاف تهای طراحی و ساخت غشاهای هوشمند و همچنین کاربرد گسترده آن ها در زمینه های مختلف بررسی شده است.
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1. M. Mulder, Basic Principles of Membrane Technology. Dordrecht: Springer Netherlands, 1996.
2. B. E. Logan and M. Elimelech, “Membrane-based Processes for Sustainable Power Generation Using Water,” Nature, vol. 488, no. 7411, pp. 313–319, Aug. 2012.
[3] L. D. Tijing, Y. C. Woo, J.S. Choi, S. Lee, S.H. Kim, and H. K. Shon, “Fouling Andits Control in Membrane Distillation Areview,” J. Memb. Sci., vol. 475, pp. 215–244, 2015.
[4] M. A. Shannon, P. W. Bohn, M. Elimelech, J. G. Georgiadis, B. J. Mariñas, and A. M. Mayes, “Science and Technology for Water Purification in the Coming Decades,” Nature, vol. 452, no. 7185, pp. 301–310, Mar. 2008.
[5] Y. Jiang, A. Lee, J. Chen, M. Cadene, B. T. Chait, and R. MacKinnon, “The Open Pore Conformation of Potassium Channels,” Nature, vol. 417, no. 6888, pp. 523–526, May 2002.
[6] D. Menne, F. Pitsch, J. E. Wong, A. Pich, and M. Wessling, “Temperature-Modulated Water Filtration Using Microgel-Functionalized Hollow-Fiber Membranes.,” Angew. Chem. Int. Ed. Engl., vol. 53, no. 22, pp. 5706–10, May 2014.
[7] L.Y. Chu, T. Yamaguchi, and S. Nakao, “A Molecular-Recognition Microcapsule for Environmental Stimuli-Responsive Controlled Release,” Adv. Mater., vol. 14, no. 5, p. 386, Mar. 2002.
[8] T. Meng, “A Thermo-Responsive Affinity Membrane with Nano-structured Pores and Grafted Poly(N-isopropylacrylamide) Surface Layer for Hydrophobic Adsorption,” J. Memb. Sci., vol. 349, no. 1, pp. 258–267, 2010.
[9] B. Yang and W. Yang, “Thermo-Sensitive Switching Membranes Regulated by Pore-Covering Polymer Brushes,” J. Memb. Sci., vol. 218, no. 1, pp. 247–255, 2003.
[10] M. Yang, L.-Y. Chu, H.-D. Wang, R. Xie, H. Song, and C. H. Niu, “A Thermoresponsive Membrane for Chiral Resolution,” Adv. Funct. Mater., vol. 18, no. 4, pp. 652–663, Feb. 2008.
[11] Z. Liu, W. Wang, R. Xie, X. J. Juab and L. Y. Chu, "Stimuli-Responsive Smart Gating Membranes," Chem. Soc. Rev., vol. 45, pp. 460-475, 2016
[12] Z. Liu “Gating Membranes for Water Treatment: Detection and Removal of Trace Pb2+ Ions Based on Molecular Recognition and Polymer Phase Transition,” J. Mater. Chem. A, vol. 1, no. 34, p. 9659, 2013.
[13] J. I. Clodt., “Double Stimuli-Responsive Isoporous Membranes via Post-Modification of pH-Sensitive Self-Assembled Diblock Copolymer Membranes,” Adv. Funct. Mater., vol. 23, no. 6, pp. 731–738, Feb. 2013.
[14] T. Luo., “pH-responsive Poly(ether sulfone) Composite Membranes Blended with Amphiphilic Polystyrene-Block-Poly(Acrylic Acid) Copolymers,” J. Memb. Sci., vol. 450, pp. 162–173, 2014.
[15] J. Xue., “Stimuli-Responsive Multifunctional Membranes of Controllable Morphology from Poly(vinylidene fluoride)- graft -Poly[2-( N,N -dimethylamino)ethyl methacrylate] Prepared via Atom Transfer Radical Polymerization,” Langmuir, vol. 24, no. 24, pp. 14151–14158, Dec. 2008.
[16] F. Luo., “Smart Gating Membranes with in Situ Self-Assembled Responsive Nanogels as Functional Gates,” Sci. Rep., vol. 5, p. 14708, Oct. 2015.
[17] D, Schmaljohann, “Thermo- and pH-Responsive Polymers in Drug Delivery,” Adv. Drug Deliv. Rev., vol. 58, no. 15, pp. 1655–1670, Dec. 2006.
[18] G. Pasparakis, T. Manouras, P. Argitis, and M. Vamvakaki, “Photodegradable Polymers for Biotechnological Applications,” Macromol. Rapid Commun., vol. 33, no. 3, pp. 183–198, Feb. 2012.
[19] C. Weber, R. Hoogenboom, and U. S. Schubert, “Temperature Responsive Bio-compatible Polymers Based on Poly(Ethylene Oxide) and Poly(2-Oxazoline)s,” Prog. Polym. Sci., vol. 37, no. 5, pp. 686–714, May 2012.
[20] R. Xie, Y. Li, and L.Y. Chu, “Preparation of Thermo-Responsive Gating Membranes with Controllable Response Temperature,” J. Memb. Sci., vol. 289, no. 1, pp. 76–85, 2007.
[21] Z. Liu “Positively K + -Responsive Membranes with Functional Gates Driven by Host-Guest Molecular Recognition,” Adv. Funct. Mater., vol. 22, no. 22, pp. 4742–4750, Nov. 2012.
[22] M. Yang, R. Xie, J.Y. Wang, X.J. Ju, L. Yang, and L.Y. Chu, “Gating Characteristics of Thermo-Responsive and Molecular-Recognizable Membranes Based on Poly(N-isopropylacrylamide) and β-cyclodextrin,” J. Memb. Sci., vol. 355, no. 1, pp. 142–150, 2010.
[23] N. Liu, Z. Chen, D. R. Dunphy, Y.-B. Jiang, R. A. Assink, and C. J. Brinker, “Photoresponsive Nanocomposite Formed by Self-Assembly of an Azobenzene-Modified Silane,” Angew. Chemie Int. Ed., vol. 42, no. 15, pp. 1731–1734, Apr. 2003.
[24] L.Y. Chu, Y. Li, J.H. Zhu, H.D. Wang, and Y.J. Liang, “Control of Pore Size and Permeability of a Glucose-Responsive Gating Membrane for Insulin Delivery,” J. Control. Release, vol. 97, no. 1, pp. 43–53, 2004.
[25] A. M. Gajda., “Magnetic Fe3O4 Nanoparticle Heaters in Smart Porous Membrane Valves,” J. Mater. Chem. B, vol. 2, no. 10, p. 1317, 2014.
[26] L.Y. Chu, Y. Li, J.H. Zhu, and W. M. Chen, “Negatively Thermoresponsive Membranes with Functional Gates Driven by Zipper-TypeHydrogen-BondingInteractions,” Angew. Chemie Int. Ed., vol. 44, no. 14, pp. 2124–2127, Mar. 2005.
[27] A. Nayak, H. Liu, and G. Belfort, “An Optically Reversible Switching Membrane Surface,” Angew. Chemie Int. Ed., vol. 45, no. 25, pp. 4094–4098, Jun. 2006.
[28] G. Zhai., “Poly(vinylidene fluoride) with Grafted Zwitterionic Polymer Side Chains for Electrolyte-Responsive Microfiltration Membranes,” Langmuir, vol 19, no 17, pp. 7030–7037, 2003.
[29] Yoshihiro Ito, Shugo Nishi, and Yong Soon Park, and Y. Imanishi, “Oxidoreduction-Sensitive Control of Water Permeation through a Polymer Brushes-Grafted Porous Membrane, ”Macromolecules, vol 30, no 19, pp. 5856–5859, 1997.
